工艺与制造英文2020被引 2
聚酰胺6的合成与分析研究进展：从ε-己内酰胺聚合化学到热塑性树脂传递模塑（T-RTM）
Recent Advances in the Synthesis and Analysis of Polyamide 6 and Products Therefrom: From Polymerization Chemistry of ε-Caprolactam to Thermoplastic Resin Transfer Molding (T-RTM)
Zsófia Osváth
摘要整理
合成聚酰胺（尼龙）领域正在进行重大研究和开发工作。其中聚(ε-己内酰胺)（PCL、聚酰胺6、PA6、尼龙6）是该聚合物家族中研究最广泛的成员之一。本文概述了ε-己内酰胺（CL）阴离子开环聚合（AROP）的主要最新进展，包括金属内酰胺盐和氨基甲酰基己内酰胺的引发剂组合，以及其他引发体系如保护的N-杂环卡宾、NaHMDI和σ-硼烷-钡络合物等。讨论了在阻燃剂、增强剂和填料等添加剂存在下CL的原位聚合。介绍了利用1,1,1-三氟乙醇作为洗脱液的凝胶层析色谱法（GPC/SEC）测定聚酰胺6分子量分布（MWD）和平均分子量的方法。最后，阐述了热塑性树脂传递模塑（T-RTM）工艺的最新研究进展，该工艺通过CL的快速原位聚合制备聚酰胺6产品，如增强PA6和复合材料。
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